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May be used to comply with OSHA’s Hazard Communication Standard, 29 CFR 1910.1200. Standard must be consulted for specific requirements. This information should be given to all individuals who may come in contact with this material.
N.A. = NOT APPLICABLE N.E. = NOT ESTABLISHED
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1.0 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
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PRODUCT NAME (s): GRIFLUBEÒ ® BIO-SYN EHC (Electro Hydraulic Control Fire Resistant Hydraulic Fluid)
SYNONYMS: ISO 42
EMERGENCY
MANUFACTURER / SUPPLIER: The Hill & Griffith Co. TELEPHONE: (800) 424-9300
1085 Summer Street Call Chemtrec
Cincinnati, Ohio 45204
(513) 921-1075 Fax: (513) 921-9180
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2.0 COMPOSITION / INGREDIENT INFORMATION
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Ingredient
Non-hazardous Material Blend/
Soy Bean Oil
Performance Additive Blend |
CAS Number
Proprietary
008001-22-7
Mixture |
Range (% by Wt.)
95-100
0-5 |
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3.0 HAZARD IDENTIFICATION
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EMERGENCY OVERVIEW: Mildly toxic.
POTENTIAL HEALTH EFFECTS
EYE CONTACT: This product may cause minor eye irritation, but good hygienic practices can minimize these effects.
SKIN CONTACT: Primary route of entry. Frequent or prolonged contact may cause minor irritations to the skin or a skin rash (dermatitis). Good hygienic practices can minimize these effects.
INHALATION: Minor lung irritation could occur, but good hygienic practices can minimize these effects. Exposure to vapors of this product could also cause dizziness due to possible generation of trace amounts of hydrogen sulfide at elevated temperatures.
INGESTION: Material has a low order of acute or chronic oral toxicity.
Normal use of this product does not result in generation of an oil mist. However, if an oil mist is generated, overexposure can cause minor and reversible irritation to the eyes, skin, and especially the lungs. Proper personal protective equipment and sufficient ventilation can provide adequate protection.
CARCINOGENICITY: None of the components present in this material at concentration equal to or greater than 0.1% are listed by IARC, NTP, OSHA or ACGIH as a carcinogen.
HMIS CODE: 0 - Health, 1 - Flammability, 0 - Reactivity
NFPA CODE: 0 - Health, 1 - Flammability, 0 - Reactivity
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4.0 FIRST-AID MEASURES
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INHALATION: Remove victim from further exposure and restore breathing. Seek medical attention.
SKIN CONTACT/ABSORPTION: Wash skin thoroughly with soap and water. Remove contaminated clothing. If irritation develops, seek medical attention.
EYE CONTACT: Flush with large amounts of clear flowing water for at least 15 minutes. Hold eyelids apart to ensure rinsing of the entire surface of the eye and lids with water. If irritation persists, seek medical attention.
INGESTION: If ingested, DO NOT induce vomiting; give two glasses of water. Guard against aspiration into the lungs. If vomiting occurs, keep head below hips to prevent aspiration into the lungs. Not expected to be acutely toxic. If large amounts are swallowed, call a physician.
NOTE TO PHYSICIAN: See above.
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5.0 FIRE FIGHTING MEASURES
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FLASHPOINT: Greater than 550oF
FLAMMABLE LIMITS LEL: NEUEL: NE
AUTOIGNITION TEMPERATURE: NE
FLAMMABILITY CLASSIFICATION: IIIB Combustible Liquid
EXTINGUISHING MEDIA: Carbon dioxide, dry chemical, foam, sand.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Avoid using water as it may spread fire by dispersing oil. Water spray may be used to flush spills away from fire. Use water spray to cool exposed surfaces. Rags and waste paper containing this material or any oils may heat and burn spontaneously. Rags soaked with any oils present a fire hazard and should always be stored in UL Listed or Factory Mutual approved, covered containers. Improperly stored rags can create conditions that lead to oxidation. Oxidation, under certain conditions, can lead to spontaneous combustion.
FIRE FIGHTING EQUIPMENT: Use full turnout gear and full facepiece with self-contained breathing apparatus when fighting fires near this product.
PRECAUTIONS: Avoid streams of water, which can cause frothing of chemical or cause material to disperse.
HAZARDOUS COMBUSTION PRODUCTS: Carbon monoxide and/or carbon dioxide and potentially other toxic materials such as hydrogen sulfide may be generated. Do not enter enclosed or confined space without proper protective equipment including respiratory protection.
HAZARDOUS POLYMERIZATION: Will not occur.
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6.0 ACCIDENTAL RELEASE MEASURES
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Isolate area and limit access. Remove source of heat, sparks, and flame. Stop source of leak if possible to do so without hazard. Wear appropriate respiratory protection and protective clothing. For small spill, dike area and use solid or other inorganic absorbent, shovel into disposable container. Hose down area and clean with detergent. For large spill, dike area ahead of spill, ventilate closed areas before entry. Pump material into holding container. Clean area with detergent. Prevent material from entering waterways. If material does enter waterways, please contact the appropriate authorities immediately. In the event of an uncontrolled release of this material, the user should determine if this release is reportable under applicable laws and regulations.
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7.0 HANDLING AND STORAGE
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HANDLING: Exercise good personal hygiene including removal of soiled clothing and prompt washing with soap and water. Keep away from heat, sparks, and open flames. Fixed equipment as well as transfer containers and equipment should be grounded to prevent accumulation of static charge. Close container after each use. Do not pressurize, cut, weld, braze, solder, grind or drill on or near full or empty container. Empty container retains residue (liquid and /or vapor) and may explode in the heat of fire.
STORAGE: Always segregate materials by major hazard class. Product should be handled and stored in accordance with industry accepted practices. Store in properly closed containers that are well labeled. Store in a dry, cool, well-ventilated area. Store away from heat, open flame, strong oxidizers, or other source of ignition. Keep containers closed when not in use.
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8.0 EXPOSURE CONTROLS AND PERSONAL PROTECTION
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INHALATION PROTECTION: Use NIOSH approved respirator for organic vapor for oil mists if exposure may be above the TLV. Personal protective equipment is generally not needed.
EYE PROTECTION: Use safety glasses with side shields or goggles when transferring material to prevent material from splashing into the eye.
SKIN PROTECTION: Neoprene, Nitrile, or PVA gloves to prevent skin contact. Material is not considered a primary skin irritant.
ENGINEERING CONTROLS: Local exhaust at point of generation. Local or general exhaust required when using material at elevated temperatures, which accelerates generation of vapors.
EXPOSURE GUIDELINES:
Ingredient
Non-hazardous Material Blend/
Performance Additive Blend |
CAS Number
Proprietary
Mixture |
Range (% by Wt.)
NE for liquid 10 mg/m3 (OSHA PEL) for oil mist |
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9.0 CHEMICAL AND PHYSICAL INFORMATION
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Appearance and Odor: Pale yellow, oily liquid with slight odor.
Water Solubility: Insoluble
Boiling Range (oF): NA
Vapor Pressure (mmHg): NA
pH: NA
Evaporation Rate: NA |
Melting Point(oF): NA
Specific Gravity (water=1): 0.920-0.925
Vapor Density: > 1.0
Percent Volatile by Volume: 0% |
10.0 STABILITY AND REACTIVITY
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STABILITY: Stable under normal temperature and pressure. Spontaneous combustion can occur. See Unusual Fire and Explosion Procedures in Section 5.0.
CONDITIONS TO AVOID: High surface area exposure to oxygen can result in polymerization and release of heat.
MATERIALS TO AVOID: Strong oxidizers.
HAZARDOUS DECOMPOSITION: Carbon monoxide and carbon dioxide. Thermal decomposition may produce hydrogen sulfide at elevated temperatures.
HAZARDOUS POLYMERIZATION: Will not occur.
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11.0 TOXICOLOGICAL INFORMATION
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ACUTE TOXICITY DATA
EYE IRRITATION: Mild irritant
SKIN IRRITATION: Mild irritant
DERMAL LD50: NE
ORAL LD50: NE
INHALATION LC50: NE
OTHER TOXICITY DATA: NE
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12.0 ECOLOGICAL INFORMATION
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Not established.
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13.0 DISPOSAL INFORMATION
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Waste generated during application, demolition, breakage, or spillage may be hazardous waste as defined by RCRA (40 CFR Part 261). Place waste and spillage in closed containers. Dispose of in approved landfill in accordance with federal, state, and local regulations. Do not pollute or allow material to enter waterways. Conserve resources
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14.0 TRANSPORTATION INFORMATION
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U.S. DEPARTMENT OF TRANSPORTATION SHIPPING NAME: Biodegradable Hydraulic Oil
HAZARD CLASS: None
IDENTIFICATION NUMBER: None
LABEL(S) REQUIRED: None
INTERNATIONAL INFORMATION: None
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15.0 REGULATORY INFORMATION
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CERCLA SECTIONS 102A / 103 HAZARDOUS SUBSTANCES (40 CFR PART 302.4):
SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR PART 344): Not Regulated
SARA TITLE III SECTION 311 / 312 HAZARDOUS CATEGORIZATION (40 CFR 370): Not Regulated
SARA TITLE III SECTION 313 (40 CFR PART 372):
U.S. INVENTORY (TSCA): All ingredients listed on inventory or exempted.
OSHA HAZARD COMMUNICATION STANDARD: Under normal conditions this material is not known to be hazardous.
WHMIS CONTROLLED PRODUCT CLASSIFICATION: NE
EC INVENTORY (EINECS / ELINCS): NE
CANADA INVENTORY (DSL): NE.
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16.0 OTHER INFORMATION
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No additional information known
.
This Material Safety Data Sheet conforms to the requirements of ANSI Z400.1. As of the date of preparation of this document, the forgoing information is believed to be accurate and is provided in good faith to comply with applicable federal and state law(s). However, no warranty or representation with respect to such information is intended or given.
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Date Prepared: 01/17/2005
Prepared by: Donald J. Nuss, Jr |
Supersedes: 01/13/2004 -01/07/05
Title: Corporate Government Regulatory Manager |
Print Date: 01/17/2005 |
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As of the date of preparation of this document, the forgoing information is believed to be accurate and is provided in good faith to comply with applicable federal and state law(s). However, no warranty or representation with respect to such information is intended or given.
PRINTED IN U.S.A.
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